Volumetric determination of columbium.
نویسندگان
چکیده
The quantitative determination of columbium based on reduction by amalgamated zin c and reox idation with potassium permanganate has, in general, produced results that lack both accuracy and precision. A study of t he various factors involved indicates that essential conditions requ ire adequate duration of reduction in t he presence of an excess of zinc and a proper concentration of both acid and columbium. A procedure is described whereby columbium, in a sulfuri c acid solu t ion , is quantitatively reduced by amalgamated zinc to the t rivalent form and subsequently ox idi zed to t he quinquevalent state.
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ورودعنوان ژورنال:
- Journal of research of the National Bureau of Standards
دوره 42 4 شماره
صفحات -
تاریخ انتشار 1949