Volumetric determination of columbium.

نویسندگان

  • H B KNOWLES
  • G E F LUNDELL
چکیده

The quantitative determination of columbium based on reduction by amalgamated zin c and reox idation with potassium permanganate has, in general, produced results that lack both accuracy and precision. A study of t he various factors involved indicates that essential conditions requ ire adequate duration of reduction in t he presence of an excess of zinc and a proper concentration of both acid and columbium. A procedure is described whereby columbium, in a sulfuri c acid solu t ion , is quantitatively reduced by amalgamated zinc to the t rivalent form and subsequently ox idi zed to t he quinquevalent state.

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عنوان ژورنال:
  • Journal of research of the National Bureau of Standards

دوره 42 4  شماره 

صفحات  -

تاریخ انتشار 1949